Proof of Concept: Interface of Recyclable Organogels with Embedded Palladium Nanoparticles Catalyzing Suzuki-Miyaura Coupling in Water at Room Temperature.

ABSTRACT: A sustainable approach for C-C cross-coupling reaction at room temperature in water has been developed to avoid tedious Pd separation, reduce the carbon footprint, and save energy. Another important aspect is the catalyst recycling and easy product separation. α,γ-Hybrid peptides were designed to selectively use as a ligand for C-C cross-coupling catalysts as well as to form organogels. The peptides form antiparallel sheet-like structures in the solid state. The peptide containing m-aminobenzoic acid, glycine, and dimethylamine forms a whitish gel in toluene, and co-gelation with Pd(OAc)₂ results in light brown gel, which acts as a biphasic catalyst for Suzuki-Miyaura cross-coupling at room temperature in water by mild shaking. The organic-inorganic hybrid gel was charact

SUBMITTER: Roy Chowdhury S 

PROVIDER: S-EPMC9244900 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature