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Rapid liquid phase-assisted ultrahigh-temperature sintering of high-entropy ceramic composites.

ABSTRACT: High-entropy ceramics and their composites display high mechanical strength and attractive high-temperature stabilities. However, properties like strong covalent bond character and low self-diffusion coefficients make them difficult to get sintered, limiting their mass popularity. Here, we present a rapid liquid phase-assisted ultrahigh-temperature sintering strategy and use high-entropy metal diboride/boron carbide composite as a proof of concept. We use a carbon-based heater to fast-heat the composite to around 3000 K, and a small fraction of eutectic liquid was formed at the interface between high-entropy metal diborides and boron carbide. A crystalline dodecaboride intergranular phase was generated upon cooling to ameliorate the adhesion between the components. The as-sintered composite presents a high hardness of 36.4 GPa at a load of 0.49 N and 24.4 GPa at a load of 9.8 N. This liquid phase-assisted rapid ultrahigh-temperature strategy can be widely applicable for other ultrahigh-temperature ceramics as well.

SUBMITTER: Xie H

PROVIDER: S-EPMC9258815 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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Rapid liquid phase-assisted ultrahigh-temperature sintering of high-entropy ceramic composites.

Xie Hua H Qin Mingde M Hong Min M Rao Jiancun J Guo Miao M Luo Jian J Hu Liangbing L

Science advances 20220706 27

High-entropy ceramics and their composites display high mechanical strength and attractive high-temperature stabilities. However, properties like strong covalent bond character and low self-diffusion coefficients make them difficult to get sintered, limiting their mass popularity. Here, we present a rapid liquid phase-assisted ultrahigh-temperature sintering strategy and use high-entropy metal diboride/boron carbide composite as a proof of concept. We use a carbon-based heater to fast-heat the c ...[more]

PMID: 35857462

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Project description:The low deposition time efficiency and small thickness limit the expansion of polydopamine (PDA) application to fiber-reinforced high-temperature ceramic composites. In this work, the electric field-assisted polymerization (EFAP) route was developed to improve the deposition time efficiency of PDA coating and overcome the thickness limitation. Carbonized polydopamine (C-PDA) coating was used as the interphase of carbon fiber-reinforced ZrB2-based composites (Cf/ZrB2-based composite) to bond rigid fibers and brittle ceramics, where C-PDA coating was prepared by the carbonization of PDA coating. Firstly, uniform and dense PDA coatings were deposited on carbon fibers (Cf) by EFAP. The thickness of PDA coating reached the micron level (over 1800 nm) for the first time. Benefiting from the EFAP route promoting the oxidation process of dopamine (DA) and accelerating the aggregation and in-situ polymerization of DA and its derivatives on the surface of Cf, the deposition rate of PDA coating reached 5589 nm/h, which was 3 orders of magnitude higher than that of the traditional self-polymerization process. By adjusting the EFAP parameters (e.g. DA-concentration, current, and deposition time), the thickness of PDA coating could be conveniently designed from nano-scale to micro-scale. Then, PDA coating was pyrolyzed to obtain C-PDA coating. C-PDA coating was well bonded on Cf without visible cross-sticking among neighboring fibers. C-PDA coating presented a layered structure and the thickness of C-PDA coating could be designed by controlling the thickness of PDA. C-PDA coating was used as the interfacial phase of the Cf/ZrB2-based composite, which ensured that the composite possessed good load-bearing capacity and thermal stability. Moreover, extraordinary damage resistance of the composite was achieved, with work of fracture up to 9936 ± 548 J/m2 at room temperature and 19,082 ± 3458 J/m2 at 1800 °C. The current work provides a high time efficiency processing route for depositing PDA coating on carbon fibers and demonstrates the attractive potential of PDA coating in fiber-reinforced high-temperature ceramic composites.

Dataset Information

Rapid liquid phase-assisted ultrahigh-temperature sintering of high-entropy ceramic composites.

Publications

Rapid liquid phase-assisted ultrahigh-temperature sintering of high-entropy ceramic composites.

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