Photoinduced large polaron transport and dynamics in organic-inorganic hybrid lead halide perovskite with terahertz probes.

ABSTRACT: Organic-inorganic hybrid metal halide perovskites (MHPs) have attracted tremendous attention for optoelectronic applications. The long photocarrier lifetime and moderate carrier mobility have been proposed as results of the large polaron formation in MHPs. However, it is challenging to measure the effective mass and carrier scattering parameters of the photogenerated large polarons in the ultrafast carrier recombination dynamics. Here, we show, in a one-step spectroscopic method, that the optical-pump and terahertz-electromagnetic probe (OPTP) technique allows us to access the nature of interplay of photoexcited unbound charge carriers and optical phonons in polycrystalline CH₃NH₃PbI₃ (MAPbI₃) of about 10 μm grain size. Firstly, we demonstrate a

SUBMITTER: Jin Z 

PROVIDER: S-EPMC9259629 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature