Solution Synthesis and Characterization of a Long and Curved Graphene Nanoribbon with Hybrid Cove-Armchair-Gulf Edge Structures.

ABSTRACT: Curved graphene nanoribbons (GNRs) with hybrid edge structures have recently attracted increasing attention due to their unique band structures and electronic properties as a result of their nonplanar conformation. This work reports the solution synthesis of a long and curved multi-edged GNR (cMGNR) with unprecedented cove-armchair-gulf edge structures. The synthesis involves an efficient A₂ B₂ -type Diels-Alder polymerization between a diethynyl-substituted prefused bichrysene monomer (3b) and a dicyclopenta[e,l]pyrene-5,11-dione derivative (6) followed by FeCl₃ -mediated Scholl oxidative cyclodehydrogenation of the obtained polyarylenes (P1). Model compounds 1a and 1b are first synthesized to examine the suitability and efficiency of the corresponding pol

SUBMITTER: Yang L 

PROVIDER: S-EPMC9259722 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature