A PtPdCoCuNi high-entropy alloy nanocatalyst for the hydrogenation of nitrobenzene.

ABSTRACT: High-entropy alloys (HEAs) with multiple elements in near-equiatomic proportions hold great promise in heterogeneous catalysis because of their exceptional physicochemical properties governed by synergy. Herein, we prepared PtPdCoCuNi HEA nanoparticles via a one-step colloid-based route and tested their catalytic performance for nitrobenzene hydrogenation to aniline. The SiO₂ supported PtPdCoCuNi displays 93.9% yield of aniline at 80 °C, which is 2.11 times that of PtPd/SiO₂. Even at room temperature, a 47.4% yield of aniline is attained with the PtPdCoCuNi/SiO₂ catalyst. DRIFTS experiments indicate formation of isolated Pt and Pd sites after alloying the transition metals and evidence a stronger interaction between the HEA catalyst and nitrobenzene.

SUBMITTER: Lu F 

PROVIDER: S-EPMC9260516 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature