Incorporating heterogeneous lacunary Keggin anions as efficient catalysts for solvent-free cyanosilylation of aldehydes and ketones.

ABSTRACT: Polyoxometalates (POMs) as efficient catalysts can be used a wide range of chemical transformations due to their tunable Brønsted/Lewis-acidity and redox properties. Herein, we reported two hybrid and heterogeneous lacunary Keggin catalysts: (TBA)₇[PW₁₁O₃₉] (TBA-PW₁₁) and (TBA)₈[SiW₁₁O₃₉]·4H₂O (TBA-SiW₁₁) (TBA⁺: tetrabutylammonium) in which [XW₁₁O₃₉]^n- anions were coated by TBA⁺ cations. In this form, TBA⁺ can easily trap reactants on the surface of the catalysts and increase the catalytic reaction. Therefore, the catalytic performance of both POMs was tested in cyanosilylation of numerous compounds bearing-carbonyl group and t

SUBMITTER: Malmir M 

PROVIDER: S-EPMC9262904 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature