Supramolecular cis-"Bis(Chelation)" of [M(CN)₆]^3- (M = Cr^III, Fe^III, Co^III) by Phloroglucinol (H₃PG).

ABSTRACT: Studies on molecular co-crystal type materials are important in the design and preparation of easy-to-absorb drugs, non-centrosymmetric, and chiral crystals for optical performance, liquid crystals, or plastic phases. From a fundamental point of view, such studies also provide useful information on various supramolecular synthons and molecular ordering, including metric parameters, molecular matching, energetical hierarchy, and combinatorial potential, appealing to the rational design of functional materials through structure-properties-application schemes. Co-crystal salts involving anionic d-metallate coordination complexes are moderately explored (compared to the generality of co-crystals), and in this context, we present a new series of isomorphous co-crystalline salts (PPh

SUBMITTER: Jedrzejowska K 

PROVIDER: S-EPMC9268030 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature