Synthesis and Characterization of Vanillin-Based π-Conjugated Polyazomethines and Their Oligomer Model Compounds.

ABSTRACT: The synthesis of π-conjugated polymers via an environmentally friendly procedure is generally challenging. Herein, we describe the synthesis of divanillin-based polyazomethines, which are derived from a potentially bio-based monomer. The polymerization is performed in 5 min under microwave irradiation without any metallic catalyst, with water as the only by-product. The vanillin-based polyazomethines were characterized by SEC, TGA, and UV-Vis spectroscopy. Model compounds were designed and characterized by X-ray diffraction and UV-Vis spectroscopy. The structure/properties study of vanillin-based azomethines used as models allowed us to unequivocally confirm the E configuration and to highlight the cross-conjugated nature of divanillin-based polymers.

SUBMITTER: Giraud L 

PROVIDER: S-EPMC9268122 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature