Direct Utilization of Near-Infrared Light for Photooxidation with a Metal-Free Photocatalyst.

ABSTRACT: Near-infrared (NIR) light-triggered photoredox catalysis is highly desirable because NIR light occupies almost 50% of solar energy and possesses excellent penetrating power in various media. Herein we utilize a metal-free boron dipyrromethene (BODIPY) derivative as the photocatalyst to achieve NIR light (720 nm LED)-driven oxidation of benzylamine derivatives, sulfides, and aryl boronic acids. Compared to blue light-driven photooxidation using Ru(bpy)₃Cl₂ as a photocatalyst, NIR light-driven photooxidation exhibited solvent independence and superior performance in large-volume (20 mL) reaction, presumably thanks to the neutral structure of a BODIPY photocatalyst and the deeper penetration depth of NIR light. We further demonstrate the application of this metal-free NI

SUBMITTER: Zeng L 

PROVIDER: S-EPMC9268673 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature