Cation-selective two-dimensional polyimine membranes for high-performance osmotic energy conversion.

ABSTRACT: Two-dimensional (2D) membranes are emerging candidates for osmotic energy conversion. However, the trade-off between ion selectivity and conductivity remains the key bottleneck. Here we demonstrate a fully crystalline imine-based 2D polymer (2DPI) membrane capable of combining excellent ionic conductivity and high selectivity for osmotic energy conversion. The 2DPI can preferentially transport cations with Na⁺ selectivity coefficient of 0.98 (Na⁺/Cl^- selectivity ratio ~84) and K⁺ selectivity coefficient of 0.93 (K⁺/Cl^- ratio ~29). Moreover, the nanometer-scale thickness (~70 nm) generates a substantially high ionic flux, contributing to a record power density of up to ~53 W m^-2, which is superior to most of nanopo

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC9270359 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature