Importance of an Axial Ln^III-F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues.

ABSTRACT: The recently reported compound [Dy^IIILF](CF₃SO₃)₂·H₂O (L = 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraaza-cyclododecane) displays a strong axial magnetic anisotropy, due to the short axial Dy-F bond, and single-molecule magnet (SMM) behavior. Following our earlier [Dy^IIILF]²⁺ work, herein we report the systematic structural and magnetic study of a family of [Ln^IIILF](CF₃SO₃)₂·H₂O compounds (Ln(III) = 1-Ce, 2-Pr, 3-Nd, 4-Eu, 5-Tb, 6-Ho, 7-Er, 8-Tm, and 9-Yb). From this series, the Ce(III) and Nd(III) analogues show slow relaxation of the magnetization under an applied direct current magnetic f

SUBMITTER: Regincos Marti E 

PROVIDER: S-EPMC9275778 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature