Temperature-Dependent Nitrous Oxide/Carbon Dioxide Preferential Adsorption in a Thiazolium-Functionalized NU-1000 Metal-Organic Framework.

ABSTRACT: Solvent-assisted ligand incorporation (SALI) of the ditopic linker 5-carboxy-3-(4-carboxybenzyl)thiazolium bromide [(H₂PhTz)Br] into the zirconium metal-organic framework NU-1000 [Zr₆O₄(OH)₈(H₂O)₄(TBAPy)₂, where NU = Northwestern University and H₄TBAPy = 1,3,6,8-tetrakis(p-benzoic-acid)pyrene], led to the SALIed NU-1000-PhTz material of minimal formula [Zr₆O₄(OH)₆(H₂O)₂(TBAPy)₂(PhTz)]Br. NU-1000-PhTz has been thoroughly characterized in the solid state. As confirmed by powder X-ray diffraction, this material keeps the same three-dimensional architecture of NU-1000 and the dica

SUBMITTER: Mercuri G 

PROVIDER: S-EPMC9280722 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature