Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors.

ABSTRACT: Two new sulfur- and selenium-rich pentacyclic aromatic compounds were prepared by short chemical syntheses. The two donors readily formed charge transfer (CT) complexes upon reaction with antimony pentachloride or tris(4-bromophenyl)ammoniumyl hexachloroantimonate. The X-ray structures of the heterocyclic donors and their CT complexes were determined. The donors flattened considerably upon CT complex formation.

SUBMITTER: Qin Q 

PROVIDER: S-EPMC9281308 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature