Fe₃O₄@PDA/MIL-101(Cr) as magnetic solid-phase extraction sorbent for mycotoxins in licorice prior to ultrahigh-performance liquid chromatography-tandem mass spectrometry analysis.

ABSTRACT: Magnetic solid-phase extraction (MSPE) strategy based on the Fe₃O₄@PDA/MIL-101(Cr) has been proposed to separate and purify five common mycotoxins in licorice, including aflatoxin B₁, aflatoxin G₁, sterigmatocystin, zearalenone, and ochratoxin A. Integrating the MSPE and solid-liquid extraction/partitioning, a modified QuEChERS was established to adapt to the complex licorice samples. The Fe₃O₄@PDA/MIL-101(Cr) was successfully synthesized and characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen adsorption-desorption isotherms. Sorbents with superior advantages for exclusion of matrix interference and extraction of target ana

SUBMITTER: Tang Z 

PROVIDER: S-EPMC9281945 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature