Chiral Luminescent Liquid Crystal with Multi-State-Reversibility: Breakthrough in Advanced Anti-Counterfeiting Materials.

ABSTRACT: Creating a security material that carries distinct information in reflective color, fluorescence, and chiroptical property will enhance anti-counterfeiting levels to deter counterfeits ranging from currencies to pharmaceuticals, but is proven extremely challenging. In this work, an advanced anti-counterfeiting material, with three-state of each mode reversibly converted into multi-mode materials including reflective color, fluorescence, and circularly polarized luminescence signal, is constructed by loading photofluorochromic spiropyran (SP) and zinc ion (Zn²⁺ ) into the chiral liquid crystal. Under UV irradiation, the complexes of SP and Zn²⁺ will be transformed into merocyanine (MC) and MC-Zn²⁺ , while the energy transfer occurs from MC-Zn²⁺ to

SUBMITTER: Shi Y 

PROVIDER: S-EPMC9284135 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature