Kinetic Stabilization of Blue-Emissive Anthracenes: Phenylene Bridging Works Best.
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ABSTRACT:
SUBMITTER: Nathusius M
PROVIDER: S-EPMC9293334 | biostudies-literature | 2021 Dec
REPOSITORIES: biostudies-literature
Publications
Kinetic Stabilization of Blue-Emissive Anthracenes: Phenylene Bridging Works Best.
Nathusius Marvin M Sleeman Daniel D Pan Junyou J Rominger Frank F Freudenberg Jan J Bunz Uwe H F UHF Müllen Klaus K
Chemistry (Weinheim an der Bergstrasse, Germany) 20211012 67
In attempts at kinetically stabilizing blue-emissive anthracenes, a series of 9,10-diaryl substituted derivatives were tested for their photochemical and photooxidative persistence. A major breakthrough in light fastness comes from a new bis-meta-terphenylyl substituted anthracene which is much superior to industrially relevant 9,10-biarylated anthracenes. The key issue is the steric shielding of the anthracene core. Further, intramolecular ring closure via Yamamoto coupling furnished a doubly b ...[more]
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