Interlayer Coordination of Pd-Pd Units in Exfoliated Black Phosphorus.

ABSTRACT: The chemical functionalization of 2D exfoliated black phosphorus (2D BP) continues to attract great interest, although a satisfactory structural characterization of the functionalized material has seldom been achieved. Herein, we provide the first complete structural characterization of 2D BP functionalized with rare discrete Pd₂ units, obtained through a mild decomposition of the organometallic dimeric precursor [Pd(η³-C₃H₅)Cl]₂. A multitechnique approach, including HAADF-STEM, solid-state NMR, XPS, and XAS, was used to study in detail the morphology of the palladated nanosheets (Pd₂/BP) and to unravel the coordination of Pd₂ units to phosphorus atoms of 2D BP. In particular, XAS, backed up by DFT modeling, revea

SUBMITTER: Vanni M 

PROVIDER: S-EPMC9295127 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature