Isolation of an Elusive Phosphametallacyclobutadiene and Its Role in Reversible Carbon-Carbon Bond Cleavage.

ABSTRACT: The reactivity of phosphaalkynes, the isolobal and isoelectronic congeners to alkynes, with metal alkylidyne complexes is explored in this work. Treating the tungsten alkylidyne [^t BuOCO]W≡C^t Bu(THF)₂ (1) with phosphaalkyne (10) results in the formation of [O₂ C(^t BuC=)W{η² -(P,C)-P≡C-Ad}(THF)] (13-^t Bu_THF ) and [O₂ C(AdC=)W{η² -(P,C)-P≡C-^t Bu}(THF)] (13-Ad_THF ); derived from the formal reductive migratory insertion of the alkylidyne moiety into a W-C_arene bond. Analogous to alkyne metathesis, a stable phosphametallacyclobutadiene complex [^t BuOCO]W[κ² -C(^t Bu)PC(Ad)] (14) forms upon loss of THF from the coordination

SUBMITTER: Jakhar VK 

PROVIDER: S-EPMC9296546 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature