Porous Single-Crystalline Monolith to Enhance Catalytic Activity and Stability.

ABSTRACT: Engineering the catalytic activity and stability of materials would require the identification of the structural features that can tailor active sites at surfaces. Porous single crystals combine the ordered lattice structures and disordered interconnected pores, and they would therefore provide the advantages of precise structure features to identify and engineer the active sites at surfaces. Herein, we fabricate porous single-crystalline vanadium nitride (VN) at centimeter scale and further dope Fe (Fe_0.1V_0.9N) and Co (Co_0.1V_0.9N) in lattice to engineer the active sites at surface. We demonstrate that the active surface is composed of unsaturated coordination of V-N, Fe-N, and Co-N structures which lead to the generation of high-density active s

SUBMITTER: Yu X 

PROVIDER: S-EPMC9297723 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature