Variable Luminescence and Chromaticity of Homoleptic Frameworks of the Lanthanides together with Pyridylpyrazolates.

ABSTRACT: Homoleptic, 3D coordination polymers of the formula ³³ _∞ [Ln(3-PyPz)₃ ] and ³ _∞ [Ln(4-PyPz)₃ ], (3-PyPz)^- =3-(3-pyridyl)pyrazolate anion, (4-PyPz)^- =3-(4-pyridyl)pyrazolate anion, both C₈ H₆ N₃ ^- , Ln=Sm, Eu, Gd, Tb, Dy, were obtained as highly luminescent frameworks by reaction of the lanthanide metals (Ln) with the aromatic heterocyclic amine ligands 3-PyPzH and 4-PyPzH. The compounds form two isotypic series of 3D coordination polymers and exhibit fair thermal stability up to 360 °C. The luminescence properties of all ten compounds were determined in the solid state, with an antenna effect through ligand-metal energy transfer leading to high efficiency of t

SUBMITTER: Youssef H 

PROVIDER: S-EPMC9298041 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature