Rhodium Indenyl NHC and Fluorenyl-Tethered NHC Half-Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C-H Borylation of Arenes and Alkanes.

ABSTRACT: Indenyl (Ind) rhodium N-heterocyclic carbene (NHC) complexes [Rh(η⁵ -Ind)(NHC)(L)] were synthesised for 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene (SIPr) with L=C₂ H₄ (1), CO (2 a) and cyclooctene (COE; 3), for 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene (SIMes) with L=CO (2 b) and COE (4), and 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) with L=CO (2 c) and COE (5). Reaction of SIPr with [Rh(Cp*)(C₂ H₄ )₂ ] did not give the desired SIPr complex, thus demonstrating the "indenyl effect" in the synthesis of 1. Oxidative addition of HSi(OEt)₃ to 3 proceeded under mild conditions to give the Rh silyl hydride complex [Rh(Ind){Si(OEt)₃ }(H)(SIPr)] (6) with loss of

SUBMITTER: Evans KJ 

PROVIDER: S-EPMC9299238 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature