A Genuine Stannylone with a Monoatomic Two-Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand.

ABSTRACT: The monoatomic zero-valent tin complex (stannylone) {[Si^II (Xant)Si^II ]Sn⁰ } 5 stabilized by a bis(silylene)xanthene ligand, [Si^II (Xant)Si^II =PhC(NtBu)₂ Si(Xant)Si(NtBu)₂ CPh], and its bis-tetracarbonyliron complex {[Si^II (Xant)Si^II ]Sn⁰ [Fe(CO)₄ ]₂ } 4 are reported. The stannylone 5 bearing a two-coordinate zero-valent tin atom is synthesized by reduction of the precursor 4 with potassium graphite. Compound 4 results from the Sn^II halide precursor {[Si^II (Xant)Si^II ]Sn^II Cl}Cl 2 or {[Si^II (Xant)Si^II ]SnBr₂ } 3 through reductive salt-metathesis reaction with K₂ Fe(CO)

SUBMITTER: Xu J 

PROVIDER: S-EPMC9300062 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature