H₂ S Dosimetry by CuO: Towards Stable Sensors by Unravelling the Underlying Solid-State Chemistry.

ABSTRACT: The precise detection of the toxic gas H₂ S requires reliable sensitivity and specificity of sensors even at minute concentrations of as low as 10 ppm, the value corresponding to typical exposure limits. CuO can be used for H₂ S dosimetry, based on the formation of conductive CuS and the concomitant significant increase in conductance. In theory, at elevated temperature the reaction is reversed and CuO is formed, ideally enabling repeated and long-term use of one sensor. Yet, the performance of CuO tends to drop upon cycling. Utilizing defined CuO nanorods we thoroughly elucidated the associated detrimental chemical changes directly on the sensors, by Raman and electron microscopy analysis of each step during sensing (CuO→CuS) and regeneration (CuS→CuO) cycles. We fin

SUBMITTER: Werner S 

PROVIDER: S-EPMC9300071 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature