Melting Temperature Depression and Phase Transitions of Nitrate-Based Molten Salts in Nanoconfinement.

ABSTRACT: Hybrids of nitrate-based molten salts (KNO₃, NaNO₃, and Solar Salt) and anodic aluminum oxide (AAO) with various pore sizes (between 25 and 380 nm) were designed for concentrated solar power (CSP) plants to achieve low melting point (<200 °C) and high thermal conductivity (>1 W m^-1 K^-1). AAO pore surfaces were passivated with octadecyl phosphonic acid (ODPA), and the results were compared with as-anodized AAO. The change in phase transition temperatures and melting temperatures of salts was investigated as a function of pore diameter. Melting temperatures decreased for all salts inside AAO with different pore sizes while the highest melting temperature decrease (ΔT = 173 ± 2 °C) was observed for KNO₃ filled in AAO with a pore di

SUBMITTER: Yazlak MG 

PROVIDER: S-EPMC9301948 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature