A Persistent Phosphanyl-Substituted Thioketyl Radical Anion.

ABSTRACT: Alkali metal salts, M⁺ [Ter(iPr)P-C(=S)-P(iPr)₂ S]^.- (M=Na, K; 2_M; Ter=2,6-bis-(2,4,6-trimethylphenyl)phenyl) containing a room-temperature-stable thioketyl radical anion were obtained by reduction of the thioketone precursor, Ter(iPr)P-C(=S)-P(iPr)₂ S (1), with alkali metals (Na, K). Single-crystal X-ray studies as well as EPR spectroscopy revealed the unequivocal existence of a thioketyl radical anion in the solid state and in solution, respectively. The computed Mulliken spin density within 2_M is mainly located at the sulfur (49 %) and the carbonyl carbon (33 %) atoms. Upon adding [2.2.2]-cryptand to the radical species 2_K to minimize the interionic interaction, an activation reaction was observed, yielding a potassium salt with a phosphany

SUBMITTER: Szych LS 

PROVIDER: S-EPMC9303638 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature