Alkali Metal Based Triimidosulfite Cages as Versatile Precursors for Single-Molecule Magnets.
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ABSTRACT: Based on the potassium [{S(tBuN)2 (tBuNH)}2 K3 (tmeda)-K3 {(HNtBu)(NtBu)2 S}2 ] (1) and sodium precursors [S(tBuN)3 (thf)3 -Na3 SNa3 (thf)3 (NtBu)3 S] (2), [S(tBuN)3 (thf)3 Na3 {(HNtBu)(NtBu)2 S}] (3) and [(tmeda)3 S-{Na3 (NtBu)3 S}2 ] (4) the syntheses and magnetic properties of three mixed metal triimidosulfite based alkali-lanthanide-metal-cages [(tBuNH)Dy{K(0.5tmeda)}2 {(NtBu)3 S}2 ]n (5) and [ClLn{Na(thf)}2 {(NtBu)3 S}2 ] with Ln=Dy (6), Er (7) are reported. The corresponding potassium (1) and
SUBMITTER: Luert D
PROVIDER: S-EPMC9304269 | biostudies-literature | 2022 Mar
REPOSITORIES: biostudies-literature
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