Interfacial Manganese-Doping in CsPbBr₃ Nanoplatelets by Employing a Molecular Shuttle.

ABSTRACT: Mn-doping in cesium lead halide perovskite nanoplatelets (NPls) is of particular importance where strong quantum confinement plays a significant role towards the exciton-dopant coupling. In this work, we report an immiscible bi-phasic strategy for post-synthetic Mn-doping of CsPbX₃ (X=Br, Cl) NPls. A systematic study shows that electron-donating oleylamine acts as a shuttle ligand to transport MnX₂ through the water-hexane interface and deliver it to the NPls. The halide anion also plays an essential role in maintaining an appropriate radius of Mn²⁺ and thus fulfilling the octahedral factor required for the formation of perovskite crystals. By varying the thickness of parent NPls, we can tune the dopant incorporation and, consequently, the exciton-to-dopant

SUBMITTER: Wu L 

PROVIDER: S-EPMC9305410 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature