Tetra-Substituted p-Tert-Butylcalix[4]Arene with Phosphoryl and Salicylamide Functional Groups: Synthesis, Complexation and Selective Extraction of f-Element Cations.
Ontology highlight
ABSTRACT: A new series of lanthanide (1-5) and uranyl (6) complexes with a tetra-substituted bifunctional calixarene ligand H2 L is described. The coordination environment for the Ln3+ and UO2 2+ ions is provided by phosphoryl and salicylamide functional groups appended to the lower rim of the p-tert-butylcalix[4]arene scaffold. Ligand interactions with lanthanide cations (light: La3+ , Pr3+ ; intermediate: Eu3+ and Gd3+ ; and heavy: Yb3+ ), as well as the uranyl cation (UO2 2+ ) is examined in the solution and solid state, respectively with spectrophotometric titration and single crystal X-ray diffractometry. The ligand is fully deprotonated in the complexation of trivalent lanth
SUBMITTER: Glasneck F
PROVIDER: S-EPMC9306641 | biostudies-literature | 2022 Feb
REPOSITORIES: biostudies-literature
ACCESS DATA
