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Versatile Chemical Recycling Strategies: Value-Added Chemicals from Polyester and Polycarbonate Waste.

ABSTRACT: Zn^II -complexes bearing half-salan ligands were exploited in the mild and selective chemical upcycling of various commercial polyesters and polycarbonates. Remarkably, we report the first example of discrete metal-mediated poly(bisphenol A carbonate) (BPA-PC) methanolysis being appreciably active at room temperature. Indeed, Zn(2)₂ and Zn(2)Et achieved complete BPA-PC consumption within 12-18 mins in 2-Me-THF, noting high bisphenol A (BPA) yields (S_BPA =85-91 %) within 2-4 h. Further kinetic analysis found such catalysts to possess k_app values of 0.28±0.040 and 0.47±0.049 min^-1 respectively at 4 wt%, the highest reported to date. A completely circular upcycling approach to plastic waste was demonstrated through the production of several renewable poly(ester-amide)s (PEAs), based on a terephthalamide monomer derived from bottle-grade poly(ethylene terephthalate) (PET), which exhibited excellent thermal properties.

SUBMITTER: Payne JM

PROVIDER: S-EPMC9306953 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature

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Versatile Chemical Recycling Strategies: Value-Added Chemicals from Polyester and Polycarbonate Waste.

Payne Jack M JM Kamran Muhammad M Davidson Matthew G MG Jones Matthew D MD

ChemSusChem 20220223 8

ZnII -complexes bearing half-salan ligands were exploited in the mild and selective chemical upcycling of various commercial polyesters and polycarbonates. Remarkably, we report the first example of discrete metal-mediated poly(bisphenol A carbonate) (BPA-PC) methanolysis being appreciably active at room temperature. Indeed, Zn(2)2 and Zn(2)Et achieved complete BPA-PC consumption within 12-18 mins in 2-Me-THF, noting high bisphenol A (BPA) yields (SBPA =85-91 %) ...[more]

PMID: 35114081

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