Mechanistic Insights into the Photoisomerization of N,N'-Disubstituted Indigos.

ABSTRACT: N,N'-disubstituted indigos are photoswitchable molecules that have recently caught the attention due to their addressability by red-light. When alkyl and aryl groups are utilized as the N-substituents, the thermal half-lives of Z isomers can be tuned independently while maintaining the advantageous red-shifted absorption spectra. To utilize these molecules in real-world applications, it is of immense importance to understand how their molecular structures as well as the environment influence their switching properties. To this end, we probed their photoisomerization mechanism by carrying out photophysical and computational studies in solvents of different polarities. The fluorescence and transient absorption experiments suggest for more polar excited and transition states, which explains t

SUBMITTER: Budzak S 

PROVIDER: S-EPMC9311193 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature