Enabling Long Cycle Life and High Rate Iron Difluoride Based Lithium Batteries by In Situ Cathode Surface Modification.

ABSTRACT: Metals fluorides (MFs) are potential conversion cathodes to replace commercial intercalation cathodes. However, the application of MFs is impeded by their poor electronic/ionic conductivity and severe decomposition of electrolyte. Here, a composite cathode of FeF₂ and polymer-derived carbon (FeF₂ @PDC) with excellent cycling performance is reported. The composite cathode is composed of nanorod-shaped FeF₂ embedded in PDC matrix with excellent mechanical strength and electronic/ionic conductivity. The FeF₂ @PDC enables a reversible capacity of 500 mAh g^-1 with a record long cycle lifetime of 1900 cycles. Remarkably, the FeF₂ @PDC can be cycled at a record rate of 60 C with a reversible capacity of 107 mAh g^-1 after

SUBMITTER: Su Y 

PROVIDER: S-EPMC9313485 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature