Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo)₂ (μ,η⁶ :η⁶ -P₆ )]: Snapshots on the Reaction Progress.

ABSTRACT: The oxidation of [(Cp*Mo)₂ (μ,η⁶ :η⁶ -P₆ )] (1) with halogens or halogen sources was investigated. The iodination afforded the ionic complexes [(Cp*Mo)₂ (μ,η³ :η³ -P₃ )(μ,η¹ :η¹ :η¹ :η¹ -P₃ I₃ )][X] (X=I₃ ^- , I^- ) (2) and [(Cp*Mo)₂ (μ,η⁴ :η⁴ -P₄ )(μ-PI₂ )][I₃ ] (3), while the reaction with PBr₅ led to the complexes [(Cp*Mo)₂ (μ,η³ :η³ -P₃ )(μ-Br)₂ ][Cp*MoBr₄ ] (4) [(Cp*MoBr)₂ (μ,η³ :η³ -P₃ )(μ,η¹ -P₂

SUBMITTER: Garbagnati A 

PROVIDER: S-EPMC9321898 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature