Radical Reactivity of the Biradical [⋅P(μ-NTer)2 P⋅] and Isolation of a Persistent Phosphorus-Cantered Monoradical [⋅P(μ-NTer)2 P-Et].
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ABSTRACT: The activation of C-Br bonds in various bromoalkanes by the biradical [⋅P(μ-NTer)2 P⋅] (1) (Ter=2,6-bis-(2,4,6-trimethylphenyl)-phenyl) is reported, yielding trans-addition products of the type [Br-P(μ-NTer)2 P-R] (2), so-called 1,3-substituted cyclo-1,3-diphospha-2,4-diazanes. This addition reaction, which represents a new easy approach to asymmetrically substituted cyclo-1,3-diphospha-2,4-diazanes, was investigated mechanistically by different spectroscopic methods (NMR, EPR, IR, Raman); the results suggested a stepwise radical reaction mechanism, as evidenced by the in-situ detection of the phosphorus-centered monoradical [⋅P(μ-NTer)2 P-R].< To provide further evidence for the radical mechanism, [⋅P(μ-NTer)2 P-Et] (3Et⋅) was synthesized direct
SUBMITTER: Rosenboom J
PROVIDER: S-EPMC9322606 | biostudies-literature | 2022 Jun
REPOSITORIES: biostudies-literature
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