Potential Anticancer Activities and Catalytic Oxidation Efficiency of Platinum(IV) Complex.

ABSTRACT: The treatment of an aqueous acetonitrile solution of chloroplatinic acid hydrate H₂PtCl₆.xH₂O and pyridine-2-carbaldehyde-oxime (paOH) in the presence of potassium thiocyanate at room temperature (25°) led to the formation of a new Pt(IV) complex with the formula [Pt(SCN)₂(paO)₂], (1). Complex 1 was fully characterized by FT-IR, UV-vis and NMR spectroscopic techniques as well as elemental analysis. The crystallographic structure of complex 1 was obtained by single-crystal X-ray diffraction. The structure of complex 1 consists of a distorted octahedral geometrical environment around the platinum center in which the coordination sites are occupied by two terminal thiocyanate ligands in trans arrangement

SUBMITTER: El-Bendary MM 

PROVIDER: S-EPMC9323151 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature