Gold(I) α-Trifluoromethyl Carbenes: Synthesis, Characterization and Reactivity Studies.

ABSTRACT: Aryl trifluoromethyl diazomethanes 2-R (R=Ph, OMe, CF₃ ) are readily decomposed by the (o-carboranyl)diphosphine gold(I) complex 1. The resulting α-CF₃ substituted carbene complexes 3-R have been characterized by multi-nuclear NMR spectroscopy as well as X-ray crystallography (for 3-Ph). The bonding situation was thoroughly assessed by computational means, showing stabilization of the electrophilic carbene center by π-donation from the aryl substituent and backdonation from Au, as enhanced by the chelating P^P ligand. Reactivity studies under stoichiometric and catalytic conditions substantiate typical carbene-type behavior for 3-Ph.

SUBMITTER: Rigoulet M 

PROVIDER: S-EPMC9323441 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature