Dataset Information
Concentrated Aqueous Peroxodicarbonate: Efficient Electrosyn- thesis and Use as Oxidizer in Epoxidations, S-, and N-Oxidations.
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ABSTRACT:
SUBMITTER: Seitz AK
PROVIDER: S-EPMC9324847 | biostudies-literature | 2022 Jun
REPOSITORIES: biostudies-literature
Publications
Concentrated Aqueous Peroxodicarbonate: Efficient Electrosyn- thesis and Use as Oxidizer in Epoxidations, S-, and N-Oxidations.
Angewandte Chemie (International ed. in English) 20220425 25
Peroxodicarbonates are of substantial interest as potentially powerful and sustainable oxidizers but have so far been accessible only in low concentrations with unsatisfactory energy efficiency. Concentrated (> 0.9 mol L<sup>-1</sup> ) peroxodicarbonate solutions have now been made accessible by the electrolysis of aqueous K<sub>2</sub> CO<sub>3</sub> /Na<sub>2</sub> CO<sub>3</sub> /KHCO<sub>3</sub> solutions at high current density of 3.33 A cm<sup>-2</sup> in an efficiently cooled circular flo ...[more]
