On the Mediated Electron Transfer of Immobilized Galactose Oxidase for Biotechnological Applications.
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ABSTRACT: The use of enzymes as catalysts in chemical synthesis offers advantages in terms of clean and highly selective transformations. Galactose oxidase (GalOx) is a remarkable enzyme with several applications in industrial conversions as it catalyzes the oxidation of primary alcohols. We have investigated the wiring of GalOx with a redox polymer; this enables mediated electron transfer with the electrode surface for its potential application in biotechnological conversions. As a result of electrochemical regeneration of the catalytic center, the formation of harmful H2 O2 is minimized during enzymatic catalysis. The introduced bioelectrode was applied to the conversion of bio-renewable platform materials, with glycerol as model substrate. The biocatalytic transformations of
SUBMITTER: Zhao F
PROVIDER: S-EPMC9325534 | biostudies-literature | 2022 May
REPOSITORIES: biostudies-literature
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