Combined Superbase Ionic Liquid Approach to Separate CO₂ from Flue Gas.

ABSTRACT: Superbase ionic liquids (ILs) with a trihexyltetradecylphosphonium cation and a benzimidazolide ([P₆₆₆₁₄][Benzim]) or tetrazolide ([P₆₆₆₁₄][Tetz]) anion were investigated in a dual-IL system allowing the selective capture and separation of CO₂ and SO₂, respectively, under realistic gas concentrations. The results show that [P₆₆₆₁₄][Tetz] is capable of efficiently capturing SO₂ in preference to CO₂ and thus, in a stepwise separation process, protects [P₆₆₆₁₄][Benzim] from the negative effects of the highly acidic contaminant. This results in [P₆₆₆₁₄][Benzim] maintaining >53% of its original CO₂ uptake capacity after 30 absorption/desorption cycles in comparison to the 89% decrease o

SUBMITTER: Greer AJ 

PROVIDER: S-EPMC9326967 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature