Enhanced Formaldehyde Oxidation Performance of the Mesoporous TiO₂(B)-Supported Pt Catalyst: The Role of Hydroxyls.

ABSTRACT: As one of the crystal phases of titania, TiO₂(B) was first utilized as a catalyst carrier for the oxidation of formaldehyde (HCHO). The mesoporous TiO₂(B) loaded with Pt nanoparticles enhanced the HCHO oxidation reaction whose reaction rate was 4.5-8.4 times those of other crystalline TiO₂-supported Pt catalysts. Simultaneously, Pt/TiO₂(B) exhibited long-term stable HCHO oxidation performance. The structural characterization results showed that in comparison with Pt/anatase, Pt/TiO₂(B) had more abundant hydroxyls, facilitating increasing the content of oxygen species. Studies on the role of hydroxyls in HCHO oxidation of Pt/TiO₂(B) illustrated that synergistic involvement of terminally bound hydroxyls and bridging hydroxyls

SUBMITTER: Wei T 

PROVIDER: S-EPMC9330097 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature