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Differences in Deterioration Behaviors of Cu/ZnO/Al2O3 Catalysts with Different Cu Contents toward Hydrogenation of CO and CO2.


ABSTRACT: The deterioration behaviors of Cu/ZnO/Al2O3 (CZA) catalysts upon different Cu contents were elucidated. The fresh and spent catalysts after being used in CO and CO2 hydrogenation at 250 °C under atmospheric pressure were properly characterized using various techniques including X-ray powder diffraction, X-ray photoelectron spectroscopy, and temperature-programmed reduction for the changes of metal sites, while the textural and chemical properties and carbon deposition on spent CZA catalysts were analyzed by N2 physisorption, energy-dispersive X-ray spectroscopy, and temperature-programmed oxidation. During the hydrogenation reaction for both CO and CO2, the unstable Cu0 site on the spent CZA catalyst having a low Cu loading

SUBMITTER: Kamsuwan T 

PROVIDER: S-EPMC9330176 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature