Hydrazine-Hydrazide-Linked Covalent Organic Frameworks for Water Harvesting.

ABSTRACT: We report a postsynthetic strategy and its implementation to make covalent organic frameworks (COFs) with irreversible hydrazide linkages. This involved the synthesis of three 2D and 3D hydrazine-linked frameworks and their partial oxidation. The linkage synthesis and functional group transformation-hydrazine and hydrazide-were evidenced by ¹⁵N multi-CP-MAS NMR. In addition, the isothermal water uptake profiles of these frameworks were studied, leading to the discovery of one hydrazine-hydrazide-linked COF suitable for water harvesting from air in arid conditions. This COF displayed characteristic S-shaped water sorption profiles, a steep pore-filling step below 18% relative humidity at 25 °C, and a total uptake capacity of 0.45 g g^-1. We found that even small changes

SUBMITTER: Nguyen HL 

PROVIDER: S-EPMC9336147 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature