Thousand-fold increase in O₂ electroreduction rates with conductive MOFs.

ABSTRACT: Molecular materials must deliver high current densities to be competitive with traditional heterogeneous catalysts. Despite their high density of active sites, it has been unclear why the reported O₂ reduction reaction (ORR) activity of molecularly defined conductive metal-organic frameworks (MOFs) have been very low: ca. -1 mA cm^-2. Here, we use a combination of gas diffusion electrolyses and nanoelectrochemical measurements to lift multiscale O₂ transport limitations and show that the intrinsic electrocatalytic ORR activity of a model 2D conductive MOF, Ni₃(HITP)₂, has been underestimated by at least 3 orders of magnitude. When it is supported on a gas diffusion electrode (GDE), Ni₃(HITP)₂ can deliver ORR activi

SUBMITTER: Mariano RG 

PROVIDER: S-EPMC9336150 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature