Solvent Gaming Chemistry to Control the Quality of Halide Perovskite Thin Films for Photovoltaics.

ABSTRACT: Research on solvent chemistry, particularly for halide perovskite intermediates, has been advancing the development of perovskite solar cells (PSCs) toward commercial applications. A predictive understanding of solvent effects on the perovskite formation is thus essential. This work systematically discloses the relationship among the basicity of solvents, solvent-contained intermediate structures, and intermediate-to-perovskite α-FAPbI₃ evolutions. Depending on their basicity, solvents exhibit their own favorite bonding selection with FA⁺ or Pb²⁺ cations by forming either hydrogen bonds or coordination bonds, resulting in two different kinds of intermediate structures. While both intermediates can be evolved into α-FAPbI₃ below the δ-to-α thermod

SUBMITTER: Huang X 

PROVIDER: S-EPMC9336153 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature