Ni single atoms on carbon nitride for visible-light-promoted full heterogeneous dual catalysis.

ABSTRACT: Visible-light-driven organic transformations are of great interest in synthesizing valuable fine chemicals under mild conditions. The merger of heterogeneous photocatalysts and transition metal catalysts has recently drawn much attention due to its versatility for organic transformations. However, these semi-heterogenous systems suffered several drawbacks, such as transition metal agglomeration on the heterogeneous surface, hindering further applications. Here, we introduce heterogeneous single Ni atoms supported on carbon nitride (NiSAC/CN) for visible-light-driven C-N functionalization with a broad substrate scope. Compared to a semi-heterogeneous system, high activity and stability were observed due to metal-support interactions. Furthermore, through systematic experimental mechanistic

SUBMITTER: Kwak M 

PROVIDER: S-EPMC9337748 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature