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Organic covalent modification to improve thermoelectric properties of TaS2.


ABSTRACT: Organic semiconductors are attracting considerable attention as a new thermoelectric material because of their molecular diversity, non-toxicity and easy processing. The side chains which are introduced into two-dimensional (2D) transition metal dichalcogenides (TMDs) by covalent modification lead to a significant decrease in their thermal conductivity. Here, we describe a simple approach to preparing the side chains covalent modification TaS2 (SCCM-TaS2) organic/inorganic hybrid structures, which is a homogeneous and non-destructive technique that does not depend on defects and boundaries. Electrical conductivity of 3,401 S cm-1 and a power factor of 0.34 mW m-1 K-2 are obtained for a hybrid material of SCCM-TaS2, with an i

SUBMITTER: Wang S 

PROVIDER: S-EPMC9338255 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature