Effects of Acidity on Reactive Oxygen Species Formation from Secondary Organic Aerosols.

ABSTRACT: Reactive oxygen species (ROS) play a critical role in the chemical transformation of atmospheric secondary organic aerosols (SOA) and aerosol health effects by causing oxidative stress in vivo. Acidity is an important physicochemical property of atmospheric aerosols, but its effects on the ROS formation from SOA have been poorly characterized. By applying the electron paramagnetic resonance spin-trapping technique and the Diogenes chemiluminescence assay, we find highly distinct radical yields and composition at different pH values in the range of 1-7.4 from SOA generated by oxidation of isoprene, α-terpineol, α-pinene, β-pinene, toluene, and naphthalene. We observe that isoprene SOA has substantial hydroxyl radical (^•OH) and organic radical yields at neutral pH, which ar

SUBMITTER: Wei J 

PROVIDER: S-EPMC9342606 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature