Solvent dielectric delimited nitro-nitrito photorearrangement in a perylenediimide derivative.

ABSTRACT: The discovery of vibrant excited-state dynamics and distinctive photochemistry has established nitrated polycyclic aromatic hydrocarbons as an exhilarating class of organic compounds. Herein, we report the atypical photorearrangement of nitro-perylenediimide (NO₂-PDI) to nitrito-perylenediimide (ONO-PDI), triggered by visible-light excitation and giving rise to linkage isomers in the polar aprotic solvent acetonitrile. ONO-PDI has been isolated and unambiguously characterized using standard spectroscopic, spectrometric, and elemental composition techniques. Although nitritoaromatic compounds are conventionally considered to be crucial intermediates in the photodissociation of nitroaromatics, experimental evidence for this has not been observed heretofore. Ultrafast transient abs

SUBMITTER: Mazumder A 

PROVIDER: S-EPMC9350666 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature