Tuning the Ground- and Excited-State Redox Potentials of Octahedral Hexanuclear Rhenium(III) Complexes by the Combination of Terminal Halide and N-Heteroaromatic Ligands.

ABSTRACT: The present study reports that the ground- and excited-state Re₆(23e)/Re₆(24e) redox potentials of an octahedral hexanuclear rhenium(III) complex can be controlled by systematically changing the number and type of the N-heteroaromatic ligand (L) and the number of chloride ions at the six terminal positions. Photoirradiation of [Re₆(μ₃-S)₈Cl₆]^4- with an excess amount of L afforded a mono-L-substituted hexanuclear rhenium(III) complex, [Re₆(μ₃-S)₈Cl₅(L)]^3- (L = 4-dimethylaminopyridine (dmap), 3,5-lutidine (lut), 4-methylpyridine (mpy), pyridine (py), 4,4'-bipyridine (bpy), 4-cyanopyridine (cpy), and pyrazine (pz)). The bis- and tris-lut-substituted comple

SUBMITTER: Yoshimura T 

PROVIDER: S-EPMC9352233 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature