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Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation.

ABSTRACT: A photo-induced C-S radical cross-coupling of aryl iodides and disulfides under transition-metal and external photosensitizer free conditions for the synthesis of aryl sulfides at room temperature has been presented, which features mild reaction conditions, broad substrate scope, high efficiency, and good functional group compatibility. The developed methodology could be readily applied to forge C-S bond in the field of pharmaceutical and material science.

SUBMITTER: Mao S

PROVIDER: S-EPMC9360480 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation.

Mao Shuai S Zhao Yahao Y Luo Zixuan Z Wang Ruizhe R Yuan Bo B Hu Jianping J Hu Linghao L Zhang San-Qi SQ Ye Xiaoxing X Wang Mingliang M Chen Zhengkai Z

Frontiers in chemistry 20220726

A photo-induced C-S radical cross-coupling of aryl iodides and disulfides under transition-metal and external photosensitizer free conditions for the synthesis of aryl sulfides at room temperature has been presented, which features mild reaction conditions, broad substrate scope, high efficiency, and good functional group compatibility. The developed methodology could be readily applied to forge C-S bond in the field of pharmaceutical and material science. ...[more]

PMID: 35958235

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