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2-Amino-4-ferrocenyl-thia-zole.

ABSTRACT: The title compound, [Fe(C5H5)(C8H7N2S)], was synthesized by the direct reaction of acetyl-ferrocene, thio-urea and resublimed iodine. The structure shows one mol-ecule in the asymmetric unit. The amino-thia-zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol-ecules inter-act via inter-molecular N-H⋯N hydrogen bonds, forming a cyclic dimer which then inter-acts with other dimers through C-H⋯π inter-actions.

SUBMITTER: Anzaldo B 

PROVIDER: S-EPMC9361361 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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2-Amino-4-ferrocenyl-thia-zole.

Anzaldo Bertin B   Sharma Pankaj P   Villamizar Claudia P CP   Gutierrez Perez Rene R   Toscano Rubén A RA  

Acta crystallographica. Section E, Crystallographic communications 20220719 Pt 8

The title compound, [Fe(C<sub>5</sub>H<sub>5</sub>)(C<sub>8</sub>H<sub>7</sub>N<sub>2</sub>S)], was synthesized by the direct reaction of acetyl-ferrocene, thio-urea and resublimed iodine. The structure shows one mol-ecule in the asymmetric unit. The amino-thia-zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol-ecules inter-act <i>via</i> inter-molecular N-H⋯N hydrogen bonds, forming a cyclic dimer which then inter-acts  ...[more]

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